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Publications
16. May, R.; Hestenes, J. C.; Munich, N.; Marbella, L. E.* "Fluorinated ether decomposition in localized high concentration electrolytes" Journal of Power Sources 2023, 553, 232299 (DOI: 10.1016/j.jpowsour.2022.232299). Special Issue in honor of Dr. Emanuel Peled
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15. Hestenes, J. C.; Sadowski, J. T.; May, R.; Marbella, L. E.* "Transition metal dissolution mechanisms and impacts on electronic conductivity in composite LiNi0.5Mn1.5O4 cathode films" ACS Materials Au 2022, Article ASAP. (DOI: 10.1021/acsmaterialsau.2c00060). Invited Issue: 2022 Rising Stars in Materials Research.
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14. Sarkar, A.*; May, R.; Valmonte, Z; Marbella, L. E.* "PolarClean and dimethyl isosorbide: green matches in formulating cathode slurry" Energy Advances 2022, 1, 671. (DOI: 10.1039/D2YA00161F).
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13. Ells, A. W.; Evans, M. L.; Groh, M. F.; Morris, A. J.*; Marbella, L. E.* "Phase transformations and phase segregation during potassiation of SnxPy anodes" Chemistry of Materials 2022, 34, 7460. (DOI: 10.1021/acs.chemmater.2c01570).
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12. Hestenes, J. C.; May, R.; Sadowski, J. T.; Munich, N.; Marbella, L. E.* "Resolving chemical and spatial heterogeneities at complex electrochemical interfaces in Li ion batteries" Chemistry of Materials 2022, 34, 232. (DOI: 10.1021/acs.chemmater.1c03185)
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11. Chang, W.‡; May, R.‡; Wang, M.; Thorsteinsson, G.; Sakamoto, J.; Marbella, L. E.*; Steingart, D.* "Evolving Contact Mechanics and Microstructure Formation Dynamics of the Lithium Metal-Li7La3Zr2O12 Interface" (‡equal contribution) Nature Communications 2021, 12, 6369. (DOI: 10.1038/s41467-021-26632-x) Selected for Editors' Highlights page on Energy
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10. Ells, A. W.; May, R.; Marbella, L. E.* "Potassium fluoride and carbonate lead to immediate cell failure in potassium-ion batteries" ACS Applied Materials & Interfaces 2021, 13, 53841. (DOI: 10.1021/acsami.1c15174)
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9. Vishnugopi, B. S.; Hao, F.; Verma, A.; Marbella, L. E.; Viswanathan, V.; Mukherjee, P. P.* "Co-electrodeposition mechanism in rechargeable metal batteries" ACS Energy Letters 2021, 6, 2190. (DOI: 10.1021/acsenergylett.1c00677)
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8. Sarkar, A.; May, R.; Ramesh, S.; Chang, W.; Marbella, L. E.* "Recovery and reuse of composite cathode binder in lithium ion batteries" ChemistryOpen 2021, 10, 545. (DOI: 10.1002/open.202100060)
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7. Russel, J.; Posey, V.; May, R.; Reed, D. A.; Marbella, L. E.; Steigerwald, M. L.; Yang, Y.; Roy, X.*; Nuckolls, C.*; Peurifoy, S. R.* “Molecular contortion as a route to high performance pseudocapacitors” Nature Materials 2021, 20, 1136. (DOI: 10.1038/s41563-021-00954-z)
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6. May, R.; Fritzsching, K.; Livitz, D.; Denny, S. R.; Marbella, L. E.* "Rapid interfacial exchange of Li ions dictates high Coulombic efficiency in Li metal anodes" ACS Energy Letters 2021, 6, 1162. (DOI: 10.1021/acsenergylett.1c00112)
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5. May, R.; Zhang, Y.; Denny, S. R.; Viswanathan, V.; Marbella, L. E.* "Leveraging Cation Identity to Engineer Solid Electrolyte Interphases for Rechargeable Lithium Metal Anodes" Cell Reports Physical Science 2020, 1, 100239. (DOI: 10.1016/j.xcrp.2020.100239)
Press release: "New Technique Extends Next-Generation Lithium Metal Batteries"

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4. Peurifoy, S. R.; Xu, Q.; May, R.; Gadjieva, N. A.; Sisto, T. J.; Jin, Z.; Marbella, L. E.; Nuckolls, C.* "Air-stable, long-length, solution-based graphene nanoribbons" Chemical Science 2020, 11, 9978. (DOI: 10.1039/D0SC02105A)
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3. Hestenes, J. C.; Ells, A. W.; Navarro Goldaraz, M.; Sergeyev, I.; Itin, B.; Marbella, L. E.* "Reversible deposition and stripping of the cathode electrolyte interphase on Li2RuO3" Frontiers in Chemistry 2020, 8, 681. (DOI: 10.3389/fchem.2020.00681) ​Invited Issue: Women in Science: Chemistry
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2. Thenuwara, A. C.; Shetty, P. P.; Kondekar, N.; Sandoval, S. E.; Cavallaro, K.; May, R.; Yang, C.-T.; Marbella, L. E.; Qi, Y.; McDowell, M. T.* "Efficient low temperature cycling of lithium metal anodes by tailoring the solid electrolyte interphase" ACS Energy Letters 2020, 5, 2411. (DOI: 10.1021/acsenergylett.0c01209).
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1. Hatzell, K. B.*; Chen, X. C.; Cobb, C. L.; Dasgupta, N. P.; Dixit, M. B.; Marbella, L. E.; McDowell, M. T.; Mukherjee, P. P.; Verma, A.; Viswanathan, V.; Westover, A. S.; Zeier, W. G. "Challenges in lithium metal anodes for solid state batteries" ACS Energy Letters 2020, 5, 922. (DOI: 10.1021/acsenergylett.9b02668) Cover Article​
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Before Columbia:

27. Torayev, A.; Engelke, S.; Su, Z.; Marbella, L. E.; De Andrade, V.; Demortiere, A.; Magusin, P. C. M. M.; Merlet, C.; Franco, A. A.; Grey, C. P. "Probing and interpreting the porosity and tortuosity evolution of Li-O2 cathodes on discharge through a combined experimental and theoretical approach" Journal of Physical Chemistry C 2021, 125, 4955. (DOI: 10.1021/acs.jpcc.0c10417)
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26. Gunnarsdóttir, A. B.; Vema, S.; Menkin, S.; Marbella, L. E.; Grey, C. P. "Investigating the effect of a fluoroethylene carbonate additive on lithium deposition and the solid electrolyte interphase in lithium metal batteries using in situ NMR spectroscopy" Journal of Materials Chemistry A 2020, 8, 14975. (DOI: 10.1039/D0TA05652A)
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25. Pesci, F. M.; Bertei, A.; Brugge, R. H.; Emge, S. P.; Hekselman, A. K. O.; Marbella, L. E.; Grey, C. P.; Aguadero, A. “Establishing Ultra-Low Activation Energies for Lithium Transport in Garnet Electrolytes” ACS Applied Materials and Interfaces 2020, 12, 32806. (DOI: 10.1021/acsami.0c08605).
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24. Marbella, L. E.; Zekoll, S.; Kasemchainan, J.; Emge, S. P.; Bruce, P. G.; Grey, C. P. “7Li NMR chemical shift imaging to detect microstructural growth of lithium in all solid-state batteries” Chemistry of Materials 2019, 31, 2762. (DOI: 10.1021/acs.chemmater.8b04875).
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23. Engelke, S.; Marbella, L. E.; Trease, N. M.; De Volder, M.; Grey, C. P. “Three-dimensional pulsed field gradient NMR measurements of self-diffusion in anisotropic materials for energy storage applications” Physical Chemistry Chemical Physics 2019, 21, 4538. (DOI: 10.1039/c8cp07776b).
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22. Royappa, A. T.; Tran, C. M.; Papoular, R. J.; Khan, M.; Marbella, L. E.; Millstone, J. E.; Gembicky, M.; Chen, B.; Shepard, W.; Elkaim, E. “Copper(I) and gold(I) thiolate precursors to bimetallic nanoparticles” Polyhedron 2018, 155, 359. (DOI: 10.1016/j.poly.2018.08.068).
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21. Griffith, K. J.; Wiaderek, K. M.; Cibin, G.; Marbella, L. E.; Grey, C. P. “Niobium tungsten oxides for high-rate lithium-ion energy storage” Nature 2018, 559, 556. (DOI: 10.1038/s41586-018-0347-0).​
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20. Jin, Y.; Kneusels, N.-J. H.; Marbella, L. E.; Castillo-Martínez, E.; Weatherup, R. S.; Magusin, P. C. M. M.; Paul, S.; Grey, C. P. “Understanding the beneficial effect of fluoroethylene carbonate and vinylene carbonate on Si anodes in Li-ion batteries” Journal of the American Chemical Society 2018, 140, 9854. (DOI: 10.1021/jacs.8b03408).
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​19. Marbella, L. E.; Evans, M. L.; Groh, M. F.; Nelson, J.; Griffith, K. J.; Morris, A. J.; Grey, C. P. “Sodiation and desodiation via helical phosphorus intermediates in high capacity phosphorus anodes for sodium-ion batteries” Journal of the American Chemical Society 2018, 140, 7794. (DOI: 10.1021/jacs.8b04183)
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18. Deringer, V. L.; Bernstein, N.; Bartók, A. P.; Cliffe, M. J.; Kerber, R. N.; Marbella, L. E.; Grey, C. P.; Elliott, S. R.; Csányi, G. “Realistic atomistic structure of amorphous silicon from machine-learning-driven molecular dynamics” Journal of Physical Chemistry Letters 2018, 9, 2879. (DOI: 10.1021/acs.jpclett.8b00902)
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17. Andolina, C. M.; Crawford, S. E.; Smith, A. M.; Johnston, K. A.; Straney, P. J.; Marbella, L. E.; Tolman, N.; Hochuli, T.; Millstone, J. E. “Near-infrared photoluminescence from small, coinage metal nanoparticles” ChemNanoMat 2018, 4, 265. (DOI: 10.1002/cnma.201700382) Cover Article
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16. Jin, Y.; Kneusels, N.-J. H.; Magusin, P. C. M. M.; Kim, G.; Castillo-Martinez, E.; Marbella, L. E.; Kerber, R. N.; Howe, D.; Paul, S.; Liu, T.; Wright, D.; Grey, C. P. “Identifying the structural basis for the increased stability of the solid electrolyte interphase formed on silicon with the additive fluoroethylene carbonate” Journal of the American Chemical Society 2017, 139, 14992. (DOI: 10.1021/jacs.7b06834)
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15. Punihaole, D.; Jakubek, R. S.; Workman, R. J.; Marbella, L. E.; Campbell, P.; Madura, J. D.; Asher, S. A. “Monomeric polyglutamine structures that evolve into fibrils” Journal of Physical Chemistry B 2017, 121, 5953. (DOI: 10.1021/acs.jpcb.7b04060)
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14. Marbella, L. E.‡; Gan, X. Y.‡; Kaseman, D. C.; Millstone, J. E. “Correlating carrier density and emergent plasmonic features in Cu2-xSe nanoparticles” Nano Letters 2017, 17, 2414. (‡equal contribution) (DOI: 10.1021/acs.nanolett.6b05420)
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13. Smith, A. M.; Johnston, K. A.; Crawford, S. E.; Marbella, L. E.; Millstone, J. E. “Ligand density quantification on colloidal inorganic nanoparticles” Analyst 2017, 142, 11. (DOI: 10.1039/C6AN02206E)
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12. ​Marbella, L. E.; Crawford, S. E.; Hartmann, M. J.; Millstone, J. E. “Observation of uniform ligand environments and 31P-197Au coupling in phosphine-terminated Au nanoparticles” Chemical Communications 2016, 52, 9020. (DOI: 10.1039/C6CC00464D) Back Cover Article
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11. Johnston, K. A.; Smith, A. M.; Marbella, L. E.; Millstone, J. E. “Impact of as-synthesized ligands and low-oxygen conditions on silver nanoparticle surface functionalization” Langmuir 2016, 32, 3820. (DOI: 10.1021/acs.langmuir.6b00232)
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10. Marbella, L. E.; Chevrier, D. M.; Tancini, P. D.; Shobayo, O.; Smith, A. M.; Johnston, K. A.; Andolina, C. M.; Zhang, P.; Mpourmpakis, G.; Millstone, J. E. “Description and role of bimetallic prenucleation species in the formation of small nanoparticle alloys” Journal of the American Chemical Society 2015, 137, 15852. (DOI: 10.1021/jacs.5b10124) ACS Select Virtual Issue JACS Young Investigators
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9. Crawford, S. E.; Andolina, C. M.; Smith, A. M.; Marbella, L. E.; Johnston, K. A.; Straney, P. J.; Hartmann, M. J.; Millstone, J. E. “Ligand-mediated ‘turn-on’ high quantum yield near-infrared emission in small gold nanoparticles” Journal of the American Chemical Society 2015, 137, 14423. (DOI: 10.1021/jacs.5b09408)
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8. Marbella, L. E.; Millstone, J. E. “NMR techniques for noble metal nanoparticles” Chemistry of Materials 2015, 27, 2721. (DOI: 10.1021/cm504809c) ACS Editors’ Choice, Cover Article
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7. Marbella, L. E.*; Yin, B.; Spence, M. M. “Investigating the order parameters of saturated lipid molecules under various curvature conditions on spherical supported lipid bilayers” Journal of Physical Chemistry B 2015, 119, 4194. (DOI: 10.1021/jp510322t)
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6. Smith, A. M.; Marbella, L. E.; Johnston, K. A.; Hartmann, M. J.; Crawford, S. E.; Kozycz, L. M.; Seferos, D. S.; Millstone, J. E. “Quantitative analysis of thiolated ligand exchange on gold nanoparticles monitored by 1H NMR spectroscopy” Analytical Chemistry 2015, 87, 2771. (DOI: 10.1021/ac504081k) ACS Select Virtual Issue NMR Developments and Applications
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5. Marbella, L. E.; Andolina, C. M.; Smith, A. M.; Hartmann, M. J.; Dewar, A. C.; Johnston, K. A.; Daly, O. H.; Millstone, J. E. “Gold-cobalt nanoparticle alloys exhibiting tunable compositions, near-infrared emission, and high T2 relaxivity” Advanced Functional Materials 2014, 24, 6532. (DOI: 10.1002/adfm.201400988)
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4. Straney, P. J.; Marbella, L. E.; Andolina, C. M.; Nuhfer, N. T.; Millstone, J. E. “Decoupling mechanisms of platinum deposition on colloidal nanoparticle substrates” Journal of the American Chemical Society 2014, 136, 7873. (DOI: 10.1021/ja504294p) JACS Spotlight
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3. Marbella, L. E.*; Cho, H. S.; Spence, M. M. “Observing the translocation of mitochondria-penetrating peptides with solid-state NMR” Biochimica et Biophysica Acta – Biomembranes 2013, 1828, 1674. (DOI: 10.1016/j.bbamem.2013.03.027)
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2. Andolina, C. M.; Dewar, A. C.; Smith, A. M.; Marbella, L. E.; Hartmann, M. J.; Millstone, J. E. “Photoluminescent gold-copper nanoparticle alloys with composition-tunable near-infrared emission” Journal of the American Chemical Society 2013, 135, 5266. (DOI: 10.1021/ja400569u)
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1. Marbella, L. E.; Serli-Mitasev, B.; Basu, P. “Development of a fluorescent Pb2+ sensor” Angewandte Chemie International Edition 2009, 48, 3996. (DOI: 10.1002/anie.200806297)
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